全文获取类型
收费全文 | 24699篇 |
免费 | 2515篇 |
国内免费 | 1329篇 |
学科分类
工业技术 | 28543篇 |
出版年
2024年 | 69篇 |
2023年 | 428篇 |
2022年 | 779篇 |
2021年 | 1158篇 |
2020年 | 882篇 |
2019年 | 661篇 |
2018年 | 735篇 |
2017年 | 862篇 |
2016年 | 752篇 |
2015年 | 1074篇 |
2014年 | 1328篇 |
2013年 | 1581篇 |
2012年 | 1765篇 |
2011年 | 1861篇 |
2010年 | 1630篇 |
2009年 | 1511篇 |
2008年 | 1466篇 |
2007年 | 1363篇 |
2006年 | 1294篇 |
2005年 | 1120篇 |
2004年 | 788篇 |
2003年 | 772篇 |
2002年 | 788篇 |
2001年 | 680篇 |
2000年 | 570篇 |
1999年 | 590篇 |
1998年 | 428篇 |
1997年 | 362篇 |
1996年 | 321篇 |
1995年 | 209篇 |
1994年 | 191篇 |
1993年 | 115篇 |
1992年 | 98篇 |
1991年 | 67篇 |
1990年 | 62篇 |
1989年 | 44篇 |
1988年 | 52篇 |
1987年 | 22篇 |
1986年 | 13篇 |
1985年 | 7篇 |
1984年 | 4篇 |
1983年 | 5篇 |
1982年 | 5篇 |
1981年 | 8篇 |
1980年 | 3篇 |
1979年 | 4篇 |
1978年 | 3篇 |
1976年 | 6篇 |
1974年 | 3篇 |
1951年 | 2篇 |
排序方式: 共有10000条查询结果,搜索用时 31 毫秒
101.
Oil–water separation has attracted research interest due to the damages of oily wastewater caused to the environment and human beings. Electrospun fiber membrane has high oil–water separation performance. A nanofibers membrane with multi-stage roughness was prepared by electrospinning using poly(vinylidene fluoride)(PVDF)-silica blend solution as raw material. The result shows that the water contact angle (WCA) of the nanofibers membrane was promoted from 138.5 ± 1° to 150.0 ± 1.5° when the SiO2 content was increased from 0 to 3 wt%. The nanofibers membranes exhibited excellent separation efficiency (99 ± 0.1%) under gravity drive, with high separation flux of 1857 ± 101 L·m−2·h−1. More importantly, the obtained PVDF-SiO2 nanofibers membranes showed excellent multi-cycle performance and stable chemical resistance, which would make them great advantages for the practical application of oil–water separation. 相似文献
102.
Wenjun Shan Ronghe Chen Qiang Zhang Jie Zhao Binbin Chen Xi Zhou Shefang Ye Shengli Bi Liming Nie Lei Ren 《Advanced materials (Deerfield Beach, Fla.)》2018,30(28)
In recent years, hepatitis B core protein virus‐like particle (HBc VLP) is an impressive biomaterial, which has attracted considerable attention due to favorable properties such as structural stability, high uptake efficiency, and biocompatibility in biomedical applications. Heretofore, only a few attempts have been made to apply it in physical, chemical, and biological therapy for cancer. In this study, a tumor‐targeting RGD‐HBc VLP is first fabricated through genetic engineering. For image‐guided cancer phototherapy, indocyanine green (ICG) is loaded into RGD‐HBc VLP via a disassembly/reassembly pathway and electrostatic attraction with high efficiency. The self‐assembled stable RGD‐HBc VLP significantly improves body retention (fourfold longer), aqueous stability, and target specificity of ICG. Remarkably, these positive reformations promote more accurate and sensitive imaging of U87MG tumor, as well as prolonged tumor destruction in comparison with free ICG. Moreover, the photothermal and photodynamic effect on tumors are quantitatively differentiated by multiple linear regression analysis. Overall, less‐potent medicinal ICG can be perfectly rescued by bioengineered HBc VLP to realize enhanced cancer optotheranostics. 相似文献
103.
Xiaowu Hu Hua Yang Tiantong Guo Dehua Shu Wenfei Shan Guizhi Li Dongcai Guo 《Ceramics International》2018,44(7):7535-7544
The long afterglow nanomaterials of strontium aluminate co-doped by Eu and Dy have been synthesized by co-precipitation combined hydrothermal method. The effects of hydrothermal time, calcination time, pH value, the amount of aluminum nitrate, activator, co-activator and flux H3BO3 on the fluorescence properties of the product were investigated by means of single factor optimization experiment. Then the orthogonal experiment was employed to obtain the optimal synthesis conditions that are as follows: nDy/nEu = 2.5, tc = 2.5?h, nEu/nSr = 0.02, th = 8?h. Subsequently, the optimal synthesis conditions were verified by three repeated experiments, and the obtained products were analyzed by X-ray diffraction (XRD), scanning electron microscopy (SEM), energy-dispersive X-ray spectroscopy (EDX) and fluorescence spectrometer. The results showed that the synthesized target products all were the mixed crystal phase of SrAl2O4 and Sr4All4O25. The particles presented regular spherical-like with size ~ 100?nm. The dopants Eu and Dy were confirmed existed in the SrAl2O4 powders. The fluorescence and afterglow data of the target products were better than that in the orthogonal experiment scheme. The primary emission spectra band was in the range of 400–600?nm with characteristic peak located at ~ 460?nm corresponding to the transitions of Eu2+ ions from 4f65d→4f7, and the blue light can be observed by naked eyes. The similar fast-decaying and slow-decaying processes were displayed in all the afterglow curves, and the initial afterglow brightness of the target product is apparently higher than that of products synthesized by the orthogonal experiment. The synthesized target products, which show excellent long afterglow performance, present a great application prospects in the aspects of ceramics, plastics, arts and crafts, ink and coating. 相似文献
104.
105.
Association of size‐fractionated indoor particulate matter and black carbon with heart rate variability in healthy elderly women in Beijing 下载免费PDF全文
W. Dong L. Pan H. Li M. R. Miller M. Loh S. Wu J. Xu X. Yang J. Shan Y. Chen F. Deng X. Guo 《Indoor air》2018,28(3):373-382
Associations between size‐fractionated indoor particulate matter (PM) and black carbon (BC) and heart rate variability (HRV) and heart rate (HR) in elderly women remain unclear. Twenty‐nine healthy elderly women were measured for 24‐hour HRV/HR indices. Real‐time size‐fractionated indoor PM and BC were monitored on the same day and on the preceding day. Mixed‐effects models were applied to investigate the associations between pollutants and HRV/HR indices. Increases in size‐fractionated indoor PM were significantly associated with declines in power in the high‐frequency band (HF), power in the low‐frequency band (LF), and standard deviation of all NN intervals (SDNN). The largest decline in HF was 19% at 5‐minute moving average for an interquartile range (IQR) increase (24 μg/m3) in PM0.5. The results showed that smaller particles could lead to greater reductions in HRV indices. The reported associations were modified by body mass index (BMI): Declines in HF at 5‐minute average for an IQR increase in PM0.5 were 34.5% and 1.0% for overweight (BMI ≥25 kg/m2) and normal‐weight (BMI <25 kg/m2) participants, respectively. Moreover, negative associations between BC and HRV indices were found to be significant in overweight participants. Increases in size‐fractionated indoor PM and BC were associated with compromised cardiac autonomic function in healthy elderly women, especially overweight ones. 相似文献
106.
107.
108.
Chen Xing Meiyu Yi Xiao Shan Xin Wang Xiaofeng Zhao Fangwei Guo 《Journal of the American Ceramic Society》2020,103(12):7267-7282
During high temperature service, a series of microstructure and phase evolutions occur in thermal barrier coatings (TBCs), which result in degradation of thermal insulation and durability. In this study, the sintering behavior of an air plasma sprayed 8 wt% YSZ coating deposited using electro-sprayed nanostructured particles (ESP) as feedstock powder was investigated and compared with conventional YSZ coating deposited using hollow spherical powders (HOSP). Due to the distinct asymmetric porous structure formed by nanosized YSZ particles, the ESP powder was partially melted in the plasma jet during the deposition, which resulted in the formation of a nanostructured coating that consisted of porous nanozones and dense zones. The ESP coating not only shows a significantly lower initial thermal conductivity of 0.70 W/mK, but also exhibits a stronger sintering resistance in terms of phase stability and thermal insulation compared to the conventional coating. When subjected to prolonged sintering at 1400°C for 128 hours, the thermal conductivity of the ESP coating would gradually increase to about half that of the HOSP coating at 1.29 W/mK. These differences are ascribed to the interaction among different sintering behavior between nanozones and dense zones. 相似文献
109.
Qiaoran Zhang Mengmeng Zhang Huili Shi Zhiwei Li Laigui Yu Xiaohong Li Zhijun Zhang Zhishen Wu 《应用聚合物科学杂志》2020,137(17):48609
110.
结合乙烯气相流化床反应工艺的特点,深入探讨分析四氢呋喃对M-1催化剂的作用和影响,结果表明,四氢呋喃的含量直接影响M-1催化剂的活性和催化乙烯与丁烯-1共聚生产的树脂产品性能。为了生产性能优良的乙烯与丁烯-1共聚产品,需要将四氢呋喃的含量严格控制在较窄的范围。 相似文献